| Datum | Spiel | Resultat |
| 09.02.2013 | Mallorca – Osasuna | 1:1 |
| 09.02.2013 | Celta Vigo – Valencia | 18.00 |
| 09.02.2013 | Levante – Malaga | 20.00 |
| 09.02.2013 | Real Madrid – FC Sevilla | 22.00 |
| 09.02.2013 | La Coruña – Granada | 22.00 |
| 10.02.2013 | FC Barcelona – Getafe | 12.00 |
| 10.02.2013 | Saragossa – Real Sociedad | 17.00 |
| 10.02.2013 | Athletic Bilbao – Espanyol Barcelona | 19.00 |
| 10.02.2013 | Rayo Vallecano – Atletico Madrid | 21.00 |
| 11.02.2013 | Betis Sevilla – Valladolid | 21.30 |
| R | Mannschaft | Sp | S | U | N | G | : | E | P |
| 1. | FC Barcelona | 22 | 19 | 2 | 1 | 72 | : | 25 | 59 |
| 2. | Atletico Madrid | 22 | 16 | 2 | 4 | 43 | : | 21 | 50 |
| 3. | Real Madrid | 22 | 13 | 4 | 5 | 54 | : | 21 | 43 |
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| 4. | Malaga | 22 | 10 | 6 | 6 | 34 | : | 20 | 36 |
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| 5. | Betis Sevilla | 22 | 11 | 2 | 9 | 31 | : | 34 | 35 |
| 6. | Valencia | 22 | 10 | 4 | 8 | 31 | : | 35 | 34 |
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| 7. | Rayo Vallecano | 22 | 11 | 1 | 10 | 31 | : | 38 | 34 |
| 8. | Real Sociedad | 22 | 9 | 6 | 7 | 35 | : | 28 | 33 |
| 9. | Levante | 22 | 10 | 3 | 9 | 28 | : | 33 | 33 |
| 10. | Valladolid | 22 | 8 | 5 | 9 | 32 | : | 29 | 29 |
| 11. | FC Sevilla | 22 | 8 | 5 | 9 | 29 | : | 30 | 29 |
| 12. | Getafe | 22 | 8 | 5 | 9 | 28 | : | 36 | 29 |
| 13. | Athletic Bilbao | 22 | 7 | 5 | 10 | 29 | : | 42 | 26 |
| 14. | Espanyol Barcelona | 22 | 6 | 7 | 9 | 26 | : | 34 | 25 |
| 15. | Saragossa | 22 | 7 | 3 | 12 | 22 | : | 31 | 24 |
| 16. | Granada | 22 | 6 | 5 | 11 | 19 | : | 32 | 23 |
| 17. | Osasuna | 23 | 5 | 7 | 11 | 19 | : | 27 | 22 |
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| 18. | Celta Vigo | 22 | 5 | 5 | 12 | 21 | : | 27 | 20 |
| 19. | Mallorca | 23 | 4 | 6 | 13 | 23 | : | 43 | 18 |
| 20. | La Coruña | 22 | 3 | 7 | 12 | 27 | : | 48 | 16 |