| Datum | Spiel | Resultat |
| 05.10.2012 | Celta Vigo – FC Sevilla | 2:0 |
| 06.10.2012 | Rayo Vallecano – La Coruña | 16.00 |
| 06.10.2012 | Saragossa – Getafe | 18.00 |
| 06.10.2012 | Valladolid – Espanyol Barcelona | 20.00 |
| 06.10.2012 | Betis Sevilla – Real Sociedad | 22.00 |
| 07.10.2012 | Levante – Valencia | 12.00 |
| 07.10.2012 | Mallorca – Granada | 16.00 |
| 07.10.2012 | Athletic Bilbao – Osasuna | 18.00 |
| 07.10.2012 | FC Barcelona – Real Madrid | 19.50 |
| 07.10.2012 | Atletico Madrid – Malaga | 21.30 |
| R | Mannschaft | Sp | S | U | N | G | : | E | P |
| 1. | FC Barcelona | 6 | 6 | 0 | 0 | 17 | : | 5 | 18 |
| 2. | Atletico Madrid | 6 | 5 | 1 | 0 | 16 | : | 7 | 16 |
| 3. | Malaga | 6 | 4 | 2 | 0 | 10 | : | 2 | 14 |
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| 4. | Mallorca | 6 | 3 | 2 | 1 | 7 | : | 4 | 11 |
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| 5. | FC Sevilla | 7 | 3 | 2 | 2 | 8 | : | 7 | 11 |
| 6. | Real Madrid | 6 | 3 | 1 | 2 | 12 | : | 5 | 10 |
| 7. | Betis Sevilla | 6 | 3 | 0 | 3 | 10 | : | 13 | 9 |
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| 8. | Real Sociedad | 6 | 3 | 0 | 3 | 8 | : | 9 | 9 |
| 9. | Valladolid | 6 | 3 | 0 | 3 | 10 | : | 6 | 9 |
| 10. | Celta Vigo | 7 | 3 | 0 | 4 | 9 | : | 8 | 9 |
| 11. | Valencia | 6 | 2 | 2 | 2 | 8 | : | 8 | 8 |
| 12. | Getafe | 6 | 2 | 1 | 3 | 7 | : | 10 | 7 |
| 13. | Levante | 6 | 2 | 1 | 3 | 7 | : | 12 | 7 |
| 14. | Rayo Vallecano | 6 | 2 | 1 | 3 | 7 | : | 13 | 7 |
| 15. | Saragossa | 6 | 2 | 0 | 4 | 5 | : | 8 | 6 |
| 16. | La Coruña | 6 | 1 | 3 | 2 | 8 | : | 12 | 6 |
| 17. | Granada | 6 | 1 | 2 | 3 | 4 | : | 9 | 5 |
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| 18. | Athletic Bilbao | 6 | 1 | 2 | 3 | 8 | : | 14 | 5 |
| 19. | Osasuna | 6 | 1 | 1 | 4 | 6 | : | 10 | 4 |
| 20. | Espanyol Barcelona | 6 | 0 | 1 | 5 | 7 | : | 12 | 1 |