| Datum | Spiel | Resultat |
| 17.08.2013 | Real Sociedad – Getafe | 2:0 |
| 17.08.2013 | Valladolid – Athletic Bilbao | 21.00 |
| 17.08.2013 | Valencia – Malaga | 23.00 |
| 18.08.2013 | FC Barcelona – Levante | 19.00 |
| 18.08.2013 | Osasuna – Granada | 21.00 |
| 18.08.2013 | Real Madrid – Betis Sevilla | 21.00 |
| 18.08.2013 | FC Sevilla – Atletico Madrid | 23.00 |
| 19.08.2013 | Rayo Vallecano – Elche | 20.00 |
| 19.08.2013 | Almeria – Villarreal | 22.00 |
| 19.08.2013 | Celta Vigo – Espanyol Barcelona | 22.00 |
| R | Mannschaft | Sp | S | U | N | G | : | E | P |
| 1. | Real Sociedad | 1 | 1 | 0 | 0 | 2 | : | 0 | 3 |
| 2. | Almeria | 0 | 0 | 0 | 0 | 0 | : | 0 | 0 |
| Athletic Bilbao | 0 | 0 | 0 | 0 | 0 | : | 0 | 0 | |
| Atletico Madrid | 0 | 0 | 0 | 0 | 0 | : | 0 | 0 | |
| Betis Sevilla | 0 | 0 | 0 | 0 | 0 | : | 0 | 0 | |
| Celta Vigo | 0 | 0 | 0 | 0 | 0 | : | 0 | 0 | |
| Elche | 0 | 0 | 0 | 0 | 0 | : | 0 | 0 | |
| Espanyol Barcelona | 0 | 0 | 0 | 0 | 0 | : | 0 | 0 | |
| FC Barcelona | 0 | 0 | 0 | 0 | 0 | : | 0 | 0 | |
| FC Sevilla | 0 | 0 | 0 | 0 | 0 | : | 0 | 0 | |
| Granada | 0 | 0 | 0 | 0 | 0 | : | 0 | 0 | |
| Levante | 0 | 0 | 0 | 0 | 0 | : | 0 | 0 | |
| Malaga | 0 | 0 | 0 | 0 | 0 | : | 0 | 0 | |
| Osasuna | 0 | 0 | 0 | 0 | 0 | : | 0 | 0 | |
| Rayo Vallecano | 0 | 0 | 0 | 0 | 0 | : | 0 | 0 | |
| Real Madrid | 0 | 0 | 0 | 0 | 0 | : | 0 | 0 | |
| Valencia | 0 | 0 | 0 | 0 | 0 | : | 0 | 0 | |
| Valladolid | 0 | 0 | 0 | 0 | 0 | : | 0 | 0 | |
| Villarreal | 0 | 0 | 0 | 0 | 0 | : | 0 | 0 | |
| 20. | Getafe | 1 | 0 | 0 | 1 | 0 | : | 2 | 0 |