| Datum | Spiel | Resultat |
| 30.08.2013 | Rayo Vallecano – Levante | 1:2 |
| 30.08.2013 | Almeria – Elche | 2:2 |
| 31.08.2013 | Celta Vigo – Granada | 19.00 |
| 31.08.2013 | Valladolid – Getafe | 21.00 |
| 31.08.2013 | Osasuna – Villarreal | 23.00 |
| 01.09.2013 | Real Madrid – Athletic Bilbao | 12.00 |
| 01.09.2013 | Espanyol Barcelona – Betis Sevilla | 17.00 |
| 01.09.2013 | Real Sociedad – Atletico Madrid | 19.00 |
| 01.09.2013 | FC Sevilla – Malaga | 21.00 |
| 01.09.2013 | Valencia – FC Barcelona | 21.00 |
| R | Mannschaft | Sp | S | U | N | G | : | E | P |
| 1. | FC Barcelona | 2 | 2 | 0 | 0 | 8 | : | 0 | 6 |
| 2. | Atletico Madrid | 2 | 2 | 0 | 0 | 8 | : | 1 | 6 |
| 3. | Athletic Bilbao | 2 | 2 | 0 | 0 | 4 | : | 1 | 6 |
|
|
|||||||||
| 4. | Villarreal | 2 | 2 | 0 | 0 | 5 | : | 3 | 6 |
|
|
|||||||||
| 5. | Real Madrid | 2 | 2 | 0 | 0 | 3 | : | 1 | 6 |
| 6. | Espanyol Barcelona | 2 | 1 | 1 | 0 | 5 | : | 3 | 4 |
|
|
|||||||||
| 7. | Real Sociedad | 2 | 1 | 1 | 0 | 3 | : | 1 | 4 |
| 8. | Celta Vigo | 2 | 1 | 1 | 0 | 4 | : | 3 | 4 |
| 9. | Levante | 3 | 1 | 1 | 1 | 2 | : | 8 | 4 |
| 10. | Granada | 2 | 1 | 0 | 1 | 2 | : | 2 | 3 |
| 11. | Valencia | 2 | 1 | 0 | 1 | 2 | : | 3 | 3 |
| 12. | Rayo Vallecano | 3 | 1 | 0 | 2 | 4 | : | 7 | 3 |
| 13. | Almeria | 3 | 0 | 2 | 1 | 6 | : | 7 | 2 |
| 14. | Elche | 3 | 0 | 2 | 1 | 3 | : | 6 | 2 |
| 15. | Getafe | 2 | 0 | 1 | 1 | 2 | : | 4 | 1 |
| 16. | FC Sevilla | 2 | 0 | 1 | 1 | 1 | : | 3 | 1 |
| 17. | Betis Sevilla | 2 | 0 | 0 | 2 | 2 | : | 4 | 0 |
| Valladolid | 2 | 0 | 0 | 2 | 2 | : | 4 | 0 | |
| 19. | Malaga | 2 | 0 | 0 | 2 | 0 | : | 2 | 0 |
| 20. | Osasuna | 2 | 0 | 0 | 2 | 1 | : | 4 | 0 |