| Datum | Spiel | Resultat |
| 14.09.2013 | Atletico Madrid – Almeria | 4:2 |
| 14.09.2013 | Levante – Real Sociedad | 18.00 |
| 14.09.2013 | FC Barcelona – FC Sevilla | 20.00 |
| 14.09.2013 | Villarreal – Real Madrid | 22.00 |
| 15.09.2013 | Granada – Espanyol Barcelona | 12.00 |
| 15.09.2013 | Getafe – Osasuna | 17.00 |
| 15.09.2013 | Malaga – Rayo Vallecano | 19.00 |
| 15.09.2013 | Betis Sevilla – Valencia | 21.00 |
| 16.09.2013 | Elche – Valladolid | 20.00 |
| 16.09.2013 | Athletic Bilbao – Celta Vigo | 22.00 |
| R | Mannschaft | Sp | S | U | N | G | : | E | P |
| 1. | Atletico Madrid | 4 | 4 | 0 | 0 | 14 | : | 4 | 12 |
| 2. | FC Barcelona | 3 | 3 | 0 | 0 | 11 | : | 2 | 9 |
| 3. | Villarreal | 3 | 3 | 0 | 0 | 8 | : | 3 | 9 |
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| 4. | Real Madrid | 3 | 3 | 0 | 0 | 6 | : | 2 | 9 |
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| 5. | Athletic Bilbao | 3 | 2 | 0 | 1 | 5 | : | 4 | 6 |
| 6. | Espanyol Barcelona | 3 | 1 | 2 | 0 | 5 | : | 3 | 5 |
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| 7. | Celta Vigo | 3 | 1 | 2 | 0 | 5 | : | 4 | 5 |
| 8. | Real Sociedad | 3 | 1 | 1 | 1 | 4 | : | 3 | 4 |
| 9. | Granada | 3 | 1 | 1 | 1 | 3 | : | 3 | 4 |
| 10. | Levante | 3 | 1 | 1 | 1 | 2 | : | 8 | 4 |
| 11. | Valladolid | 3 | 1 | 0 | 2 | 3 | : | 4 | 3 |
| 12. | Valencia | 3 | 1 | 0 | 2 | 4 | : | 6 | 3 |
| 13. | Rayo Vallecano | 3 | 1 | 0 | 2 | 4 | : | 7 | 3 |
| 14. | FC Sevilla | 3 | 0 | 2 | 1 | 3 | : | 5 | 2 |
| 15. | Elche | 3 | 0 | 2 | 1 | 3 | : | 6 | 2 |
| 16. | Almeria | 4 | 0 | 2 | 2 | 8 | : | 11 | 2 |
| 17. | Betis Sevilla | 3 | 0 | 1 | 2 | 2 | : | 4 | 1 |
| Malaga | 3 | 0 | 1 | 2 | 2 | : | 4 | 1 | |
| 19. | Getafe | 3 | 0 | 1 | 2 | 2 | : | 5 | 1 |
| 20. | Osasuna | 3 | 0 | 0 | 3 | 1 | : | 7 | 0 |