| Datum | Spiel | Resultat |
| 24.09.2013 | FC Barcelona – San Sebastian | 4:1 |
| 24.09.2013 | Levante – Valladolid | 1:1 |
| 24.09.2013 | Atletico Madrid – Osasuna | 2:1 |
| 24.09.2013 | Malaga – Almeria | 2:0 |
| 25.09.2013 | Granada – Valencia | 0:1 |
| 25.09.2013 | FC Sevilla – Rayo Vallecano | 4:1 |
| 25.09.2013 | Elche – Real Madrid | 1:2 |
| 26.09.2013 | Athletic Bilbao – Betis Sevilla | 2:1 |
| 26.09.2013 | Getafe – Celta Vigo | 22.00 |
| 26.09.2013 | Villarreal – Espanyol Barcelona | 22.00 |
| R | Mannschaft | Sp | S | U | N | G | : | E | P |
| 1. | FC Barcelona | 6 | 6 | 0 | 0 | 22 | : | 5 | 18 |
| 2. | Atletico Madrid | 6 | 6 | 0 | 0 | 18 | : | 5 | 18 |
| 3. | Real Madrid | 6 | 5 | 1 | 0 | 14 | : | 6 | 16 |
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| 4. | Athletic Bilbao | 6 | 4 | 0 | 2 | 12 | : | 10 | 12 |
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| 5. | Villarreal | 5 | 3 | 2 | 0 | 10 | : | 5 | 11 |
| 6. | Espanyol Barcelona | 5 | 3 | 2 | 0 | 9 | : | 5 | 11 |
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| 7. | Valencia | 6 | 3 | 0 | 3 | 9 | : | 10 | 9 |
| 8. | Malaga | 6 | 2 | 2 | 2 | 9 | : | 4 | 8 |
| 9. | Levante | 6 | 1 | 4 | 1 | 5 | : | 11 | 7 |
| 10. | Celta Vigo | 5 | 1 | 3 | 1 | 7 | : | 7 | 6 |
| 11. | San Sebastian | 6 | 1 | 3 | 2 | 5 | : | 7 | 6 |
| 12. | Betis Sevilla | 6 | 1 | 2 | 3 | 6 | : | 7 | 5 |
| 13. | FC Sevilla | 6 | 1 | 2 | 3 | 10 | : | 12 | 5 |
| 14. | Granada | 6 | 1 | 2 | 3 | 3 | : | 5 | 5 |
| 15. | Valladolid | 6 | 1 | 2 | 3 | 4 | : | 7 | 5 |
| 16. | Getafe | 5 | 1 | 1 | 3 | 5 | : | 10 | 4 |
| 17. | Almeria | 6 | 0 | 3 | 3 | 10 | : | 15 | 3 |
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| 18. | Elche | 6 | 0 | 3 | 3 | 5 | : | 10 | 3 |
| 19. | Osasuna | 6 | 1 | 0 | 5 | 5 | : | 12 | 3 |
| 20. | Rayo Vallecano | 6 | 1 | 0 | 5 | 5 | : | 20 | 3 |