| Datum | Spiel | Resultat |
| 04.10.2013 | Villarreal – Granada | 3:0 |
| 04.10.2013 | Malaga – Osasuna | 22.00 |
| 05.10.2013 | Elche – Espanyol Barcelona | 16.00 |
| 05.10.2013 | Rayo Vallecano – San Sebastian | 18.00 |
| 05.10.2013 | Levante – Real Madrid | 20.00 |
| 05.10.2013 | FC Barcelona – Valladolid | 22.00 |
| 06.10.2013 | Atletico Madrid – Celta Vigo | 12.00 |
| 06.10.2013 | FC Sevilla – Almeria | 17.00 |
| 06.10.2013 | Getafe – Betis Sevilla | 19.00 |
| 06.10.2013 | Athletic Bilbao – Valencia | 21.00 |
| R | Mannschaft | Sp | S | U | N | G | : | E | P |
| 1. | FC Barcelona | 7 | 7 | 0 | 0 | 24 | : | 5 | 21 |
| 2. | Atletico Madrid | 7 | 7 | 0 | 0 | 19 | : | 5 | 21 |
| 3. | Villarreal | 8 | 5 | 2 | 1 | 15 | : | 7 | 17 |
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| 4. | Real Madrid | 7 | 5 | 1 | 1 | 14 | : | 7 | 16 |
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| 5. | Athletic Bilbao | 7 | 4 | 0 | 3 | 12 | : | 12 | 12 |
| 6. | Valencia | 7 | 4 | 0 | 3 | 10 | : | 10 | 12 |
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| 7. | Espanyol Barcelona | 7 | 3 | 2 | 2 | 10 | : | 9 | 11 |
| 8. | Getafe | 7 | 3 | 1 | 3 | 9 | : | 10 | 10 |
| 9. | Levante | 7 | 2 | 4 | 1 | 6 | : | 11 | 10 |
| 10. | Malaga | 7 | 2 | 3 | 2 | 11 | : | 6 | 9 |
| 11. | Betis Sevilla | 7 | 2 | 2 | 3 | 7 | : | 7 | 8 |
| 12. | Granada | 8 | 2 | 2 | 4 | 5 | : | 8 | 8 |
| 13. | San Sebastian | 7 | 1 | 4 | 2 | 6 | : | 8 | 7 |
| 14. | Elche | 7 | 1 | 3 | 3 | 6 | : | 10 | 6 |
| 15. | Valladolid | 7 | 1 | 3 | 3 | 6 | : | 9 | 6 |
| 16. | FC Sevilla | 7 | 1 | 3 | 3 | 11 | : | 13 | 6 |
| 17. | Celta Vigo | 7 | 1 | 3 | 3 | 7 | : | 10 | 6 |
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| 18. | Almeria | 7 | 0 | 3 | 4 | 10 | : | 17 | 3 |
| 19. | Osasuna | 7 | 1 | 0 | 6 | 5 | : | 13 | 3 |
| 20. | Rayo Vallecano | 7 | 1 | 0 | 6 | 5 | : | 21 | 3 |