| Datum | Spiel | Resultat |
| 19.10.2013 | Real Madrid – Malaga | 2:0 |
| 19.10.2013 | Valencia – San Sebastian | 18.00 |
| 19.10.2013 | Osasuna – FC Barcelona | 20.00 |
| 19.10.2013 | Espanyol Barcelona – Atletico Madrid | 22.00 |
| 20.10.2013 | Granada – Getafe | 12.00 |
| 20.10.2013 | Almeria – Rayo Vallecano | 17.00 |
| 20.10.2013 | Betis Sevilla – Elche | 19.00 |
| 20.10.2013 | Valladolid – FC Sevilla | 21.00 |
| 21.10.2013 | Celta Vigo – Levante | 20.00 |
| 21.10.2013 | Athletic Bilbao – Villarreal | 22.00 |
| R | Mannschaft | Sp | S | U | N | G | : | E | P |
| 1. | FC Barcelona | 8 | 8 | 0 | 0 | 28 | : | 6 | 24 |
| 2. | Atletico Madrid | 8 | 8 | 0 | 0 | 21 | : | 6 | 24 |
| 3. | Real Madrid | 9 | 7 | 1 | 1 | 19 | : | 9 | 22 |
|
|
|||||||||
| 4. | Villarreal | 8 | 5 | 2 | 1 | 15 | : | 7 | 17 |
|
|
|||||||||
| 5. | Athletic Bilbao | 8 | 4 | 1 | 3 | 13 | : | 13 | 13 |
| 6. | Valencia | 8 | 4 | 1 | 3 | 11 | : | 11 | 13 |
|
|
|||||||||
| 7. | Getafe | 8 | 4 | 1 | 3 | 12 | : | 11 | 13 |
| 8. | Espanyol Barcelona | 8 | 3 | 2 | 3 | 11 | : | 11 | 11 |
| 9. | Levante | 8 | 2 | 4 | 2 | 8 | : | 14 | 10 |
| 10. | FC Sevilla | 8 | 2 | 3 | 3 | 13 | : | 14 | 9 |
| 11. | Elche | 8 | 2 | 3 | 3 | 8 | : | 11 | 9 |
| 12. | Malaga | 9 | 2 | 3 | 4 | 11 | : | 9 | 9 |
| 13. | Betis Sevilla | 8 | 2 | 2 | 4 | 8 | : | 10 | 8 |
| 14. | Granada | 8 | 2 | 2 | 4 | 5 | : | 8 | 8 |
| 15. | San Sebastian | 8 | 1 | 4 | 3 | 6 | : | 9 | 7 |
| 16. | Celta Vigo | 8 | 1 | 3 | 4 | 8 | : | 12 | 6 |
| 17. | Valladolid | 8 | 1 | 3 | 4 | 7 | : | 13 | 6 |
|
|
|||||||||
| 18. | Osasuna | 8 | 2 | 0 | 6 | 6 | : | 13 | 6 |
| 19. | Rayo Vallecano | 8 | 2 | 0 | 6 | 6 | : | 21 | 6 |
| 20. | Almeria | 8 | 0 | 3 | 5 | 11 | : | 19 | 3 |