| Datum | Spiel | Resultat |
| 29.10.2013 | Espanyol Barcelona – Malaga | 0:0 |
| 29.10.2013 | Celta Vigo – FC Barcelona | 0:3 |
| 30.10.2013 | Valladolid – San Sebastian | 2:2 |
| 30.10.2013 | Valencia – Almeria | 1:2 |
| 30.10.2013 | Real Madrid – FC Sevilla | 22.00 |
| 30.10.2013 | Osasuna – Rayo Vallecano | 22.00 |
| 31.10.2013 | Villarreal – Getafe | 20.00 |
| 31.10.2013 | Granada – Atletico Madrid | 20.00 |
| 31.10.2013 | Athletic Bilbao – Elche | 22.00 |
| 31.10.2013 | Betis Sevilla – Levante | 22.00 |
| R | Mannschaft | Sp | S | U | N | G | : | E | P |
| 1. | FC Barcelona | 11 | 10 | 1 | 0 | 33 | : | 7 | 31 |
| 2. | Atletico Madrid | 10 | 9 | 0 | 1 | 26 | : | 7 | 27 |
| 3. | Real Madrid | 10 | 7 | 1 | 2 | 20 | : | 11 | 22 |
|
|
|||||||||
| 4. | Villarreal | 10 | 6 | 2 | 2 | 19 | : | 10 | 20 |
|
|
|||||||||
| 5. | Athletic Bilbao | 10 | 6 | 1 | 3 | 16 | : | 13 | 19 |
| 6. | Getafe | 10 | 5 | 1 | 4 | 14 | : | 12 | 16 |
|
|
|||||||||
| 7. | Levante | 10 | 4 | 4 | 2 | 12 | : | 14 | 16 |
| 8. | Espanyol Barcelona | 11 | 4 | 3 | 4 | 12 | : | 14 | 15 |
| 9. | San Sebastian | 11 | 3 | 5 | 3 | 13 | : | 12 | 14 |
| 10. | FC Sevilla | 10 | 3 | 4 | 3 | 17 | : | 17 | 13 |
| 11. | Valencia | 11 | 4 | 1 | 6 | 14 | : | 19 | 13 |
| 12. | Elche | 10 | 3 | 3 | 4 | 10 | : | 13 | 12 |
| 13. | Granada | 10 | 3 | 2 | 5 | 6 | : | 10 | 11 |
| 14. | Valladolid | 11 | 2 | 5 | 4 | 14 | : | 17 | 11 |
| 15. | Malaga | 11 | 2 | 4 | 5 | 11 | : | 14 | 10 |
| 16. | Rayo Vallecano | 10 | 3 | 0 | 7 | 7 | : | 24 | 9 |
| 17. | Celta Vigo | 11 | 2 | 3 | 6 | 13 | : | 16 | 9 |
|
|
|||||||||
| 18. | Betis Sevilla | 10 | 2 | 2 | 6 | 9 | : | 17 | 8 |
| 19. | Osasuna | 10 | 2 | 1 | 7 | 7 | : | 15 | 7 |
| 20. | Almeria | 11 | 1 | 3 | 7 | 13 | : | 24 | 6 |