| Datum | Spiel | Resultat |
| 10.01.2014 | Granada – Valladolid | 4:0 |
| 11.01.2014 | Atletico Madrid – FC Barcelona | 16.00 |
| 11.01.2014 | Athletic Bilbao – Almeria | 18.00 |
| 11.01.2014 | Celta Vigo – Valencia | 20.00 |
| 11.01.2014 | Elche – FC Sevilla | 22.00 |
| 12.01.2014 | Getafe – Rayo Vallecano | 12.00 |
| 12.01.2014 | Betis Sevilla – Osasuna | 17.00 |
| 12.01.2014 | Espanyol Barcelona – Real Madrid | 19.00 |
| 12.01.2014 | Levante – Malaga | 21.00 |
| 13.01.2014 | Villarreal – San Sebastian | 22.00 |
| R | Mannschaft | Sp | S | U | N | G | : | E | P |
| 1. | FC Barcelona | 18 | 16 | 1 | 1 | 53 | : | 12 | 49 |
| 2. | Atletico Madrid | 18 | 16 | 1 | 1 | 47 | : | 11 | 49 |
| 3. | Real Madrid | 18 | 14 | 2 | 2 | 52 | : | 21 | 44 |
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| 4. | Athletic Bilbao | 18 | 10 | 3 | 5 | 26 | : | 23 | 33 |
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| 5. | San Sebastian | 18 | 9 | 5 | 4 | 35 | : | 23 | 32 |
| 6. | Villarreal | 18 | 9 | 4 | 5 | 32 | : | 20 | 31 |
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| 7. | FC Sevilla | 18 | 8 | 5 | 5 | 35 | : | 29 | 29 |
| 8. | Valencia | 18 | 7 | 2 | 9 | 25 | : | 29 | 23 |
| 9. | Getafe | 18 | 7 | 2 | 9 | 20 | : | 30 | 23 |
| 10. | Granada | 19 | 7 | 2 | 10 | 19 | : | 25 | 23 |
| 11. | Espanyol Barcelona | 18 | 6 | 4 | 8 | 22 | : | 24 | 22 |
| 12. | Malaga | 18 | 5 | 5 | 8 | 19 | : | 23 | 20 |
| 13. | Levante | 18 | 5 | 5 | 8 | 17 | : | 27 | 20 |
| 14. | Almeria | 18 | 5 | 4 | 9 | 20 | : | 32 | 19 |
| 15. | Osasuna | 18 | 5 | 3 | 10 | 15 | : | 28 | 18 |
| 16. | Elche | 18 | 4 | 5 | 9 | 16 | : | 27 | 17 |
| 17. | Celta Vigo | 18 | 4 | 4 | 10 | 21 | : | 30 | 16 |
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| 18. | Valladolid | 19 | 3 | 7 | 9 | 21 | : | 33 | 16 |
| 19. | Rayo Vallecano | 18 | 4 | 1 | 13 | 18 | : | 45 | 13 |
| 20. | Betis Sevilla | 18 | 2 | 5 | 11 | 15 | : | 36 | 11 |