| Datum | Spiel | Resultat |
| 31.01.2014 | Granada – Celta Vigo | 1:2 |
| 01.02.2014 | FC Barcelona – Valencia | 16.00 |
| 01.02.2014 | Levante – Rayo Vallecano | 18.00 |
| 01.02.2014 | Getafe – Valladolid | 20.00 |
| 01.02.2014 | Malaga – FC Sevilla | 22.00 |
| 02.02.2014 | Elche – Almeria | 12.00 |
| 02.02.2014 | Betis Sevilla – Espanyol Barcelona | 17.00 |
| 02.02.2014 | Atletico Madrid – San Sebastian | 19.00 |
| 02.02.2014 | Athletic Bilbao – Real Madrid | 21.00 |
| 03.02.2014 | Villarreal – Osasuna | 22.00 |
| R | Mannschaft | Sp | S | U | N | G | : | E | P |
| 1. | FC Barcelona | 21 | 17 | 3 | 1 | 57 | : | 13 | 54 |
| 2. | Atletico Madrid | 21 | 17 | 3 | 1 | 52 | : | 14 | 54 |
| 3. | Real Madrid | 21 | 17 | 2 | 2 | 60 | : | 21 | 53 |
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| 4. | Athletic Bilbao | 21 | 13 | 3 | 5 | 41 | : | 27 | 42 |
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| 5. | Villarreal | 21 | 11 | 4 | 6 | 39 | : | 22 | 37 |
| 6. | San Sebastian | 21 | 10 | 6 | 5 | 42 | : | 30 | 36 |
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| 7. | FC Sevilla | 21 | 8 | 7 | 6 | 39 | : | 34 | 31 |
| 8. | Levante | 21 | 7 | 6 | 8 | 22 | : | 30 | 27 |
| 9. | Espanyol Barcelona | 21 | 7 | 5 | 9 | 25 | : | 27 | 26 |
| 10. | Valencia | 21 | 7 | 4 | 10 | 28 | : | 33 | 25 |
| 11. | Celta Vigo | 22 | 7 | 4 | 11 | 29 | : | 35 | 25 |
| 12. | Getafe | 21 | 7 | 3 | 11 | 22 | : | 34 | 24 |
| 13. | Granada | 22 | 7 | 3 | 12 | 20 | : | 29 | 24 |
| 14. | Almeria | 21 | 6 | 4 | 11 | 22 | : | 40 | 22 |
| 15. | Osasuna | 21 | 6 | 4 | 11 | 18 | : | 34 | 22 |
| 16. | Malaga | 21 | 5 | 6 | 10 | 19 | : | 27 | 21 |
| 17. | Elche | 21 | 5 | 6 | 10 | 19 | : | 32 | 21 |
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| 18. | Valladolid | 21 | 4 | 7 | 10 | 24 | : | 37 | 19 |
| 19. | Rayo Vallecano | 21 | 5 | 1 | 15 | 21 | : | 51 | 16 |
| 20. | Betis Sevilla | 21 | 2 | 5 | 14 | 18 | : | 47 | 11 |