| Datum | Spiel | Resultat |
| 14.02.2014 | Elche – Osasuna | 0:0 |
| 15.02.2014 | Atletico Madrid – Valladolid | 16.00 |
| 15.02.2014 | Levante – Almeria | 18.00 |
| 15.02.2014 | FC Barcelona – Rayo Vallecano | 20.00 |
| 15.02.2014 | Villarreal – Celta Vigo | 22.00 |
| 16.02.2014 | Granada – Betis Sevilla | 12.00 |
| 16.02.2014 | Getafe – Real Madrid | 17.00 |
| 16.02.2014 | Athletic Bilbao – Espanyol Barcelona | 19.00 |
| 16.02.2014 | FC Sevilla – Valencia | 21.00 |
| 17.02.2014 | Malaga – San Sebastian | 22.00 |
| R | Mannschaft | Sp | S | U | N | G | : | E | P |
| 1. | FC Barcelona | 23 | 18 | 3 | 2 | 63 | : | 17 | 57 |
| 2. | Atletico Madrid | 23 | 18 | 3 | 2 | 56 | : | 16 | 57 |
| 3. | Real Madrid | 23 | 18 | 3 | 2 | 65 | : | 24 | 57 |
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| 4. | Athletic Bilbao | 23 | 13 | 5 | 5 | 42 | : | 28 | 44 |
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| 5. | Villarreal | 23 | 12 | 4 | 7 | 44 | : | 27 | 40 |
| 6. | San Sebastian | 23 | 10 | 7 | 6 | 42 | : | 34 | 37 |
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| 7. | Valencia | 23 | 9 | 4 | 10 | 36 | : | 35 | 31 |
| 8. | FC Sevilla | 23 | 8 | 7 | 8 | 42 | : | 41 | 31 |
| 9. | Levante | 23 | 7 | 8 | 8 | 22 | : | 30 | 29 |
| 10. | Espanyol Barcelona | 23 | 8 | 5 | 10 | 26 | : | 29 | 29 |
| 11. | Celta Vigo | 23 | 7 | 5 | 11 | 29 | : | 35 | 26 |
| 12. | Osasuna | 24 | 7 | 5 | 12 | 21 | : | 37 | 26 |
| 13. | Elche | 24 | 6 | 8 | 10 | 22 | : | 34 | 26 |
| 14. | Almeria | 23 | 7 | 4 | 12 | 24 | : | 41 | 25 |
| 15. | Getafe | 23 | 7 | 4 | 12 | 22 | : | 36 | 25 |
| 16. | Granada | 23 | 7 | 3 | 13 | 20 | : | 30 | 24 |
| 17. | Malaga | 23 | 6 | 6 | 11 | 23 | : | 33 | 24 |
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| 18. | Valladolid | 23 | 4 | 9 | 10 | 26 | : | 39 | 21 |
| 19. | Rayo Vallecano | 23 | 6 | 2 | 15 | 25 | : | 52 | 20 |
| 20. | Betis Sevilla | 23 | 3 | 5 | 15 | 20 | : | 52 | 14 |