| Datum | Spiel | Resultat |
| 21.02.2014 | Valladolid – Levante | 21.00 |
| 22.02.2014 | Real Madrid – Elche | 16.00 |
| 22.02.2014 | Celta Vigo – Getafe | 18.00 |
| 22.02.2014 | San Sebastian – FC Barcelona | 20.00 |
| 22.02.2014 | Almeria – Malaga | 22.00 |
| 23.02.2014 | Rayo Vallecano – FC Sevilla | 12.00 |
| 23.02.2014 | Betis Sevilla – Athletic Bilbao | 17.00 |
| 23.02.2014 | Valencia – Granada | 19.00 |
| 23.02.2014 | Osasuna – Atletico Madrid | 21.00 |
| 24.02.2014 | Espanyol Barcelona – Villarreal | 22.00 |
| R | Mannschaft | Sp | S | U | N | G | : | E | P |
| 1. | FC Barcelona | 24 | 19 | 3 | 2 | 69 | : | 17 | 60 |
| 2. | Atletico Madrid | 24 | 19 | 3 | 2 | 59 | : | 16 | 60 |
| 3. | Real Madrid | 24 | 19 | 3 | 2 | 68 | : | 24 | 60 |
|
|
|||||||||
| 4. | Athletic Bilbao | 24 | 13 | 5 | 6 | 43 | : | 30 | 44 |
|
|
|||||||||
| 5. | Villarreal | 24 | 12 | 4 | 8 | 44 | : | 29 | 40 |
| 6. | San Sebastian | 24 | 11 | 7 | 6 | 43 | : | 34 | 40 |
|
|
|||||||||
| 7. | Valencia | 24 | 9 | 5 | 10 | 36 | : | 35 | 32 |
| 8. | Levante | 24 | 8 | 8 | 8 | 23 | : | 30 | 32 |
| 9. | FC Sevilla | 24 | 8 | 8 | 8 | 42 | : | 41 | 32 |
| 10. | Espanyol Barcelona | 24 | 9 | 5 | 10 | 28 | : | 30 | 32 |
| 11. | Celta Vigo | 24 | 8 | 5 | 11 | 31 | : | 35 | 29 |
| 12. | Granada | 24 | 8 | 3 | 13 | 21 | : | 30 | 27 |
| 13. | Osasuna | 24 | 7 | 5 | 12 | 21 | : | 37 | 26 |
| 14. | Elche | 24 | 6 | 8 | 10 | 22 | : | 34 | 26 |
| 15. | Almeria | 24 | 7 | 4 | 13 | 24 | : | 42 | 25 |
| 16. | Getafe | 24 | 7 | 4 | 13 | 22 | : | 39 | 25 |
| 17. | Malaga | 24 | 6 | 6 | 12 | 23 | : | 34 | 24 |
|
|
|||||||||
| 18. | Valladolid | 24 | 4 | 9 | 11 | 26 | : | 42 | 21 |
| 19. | Rayo Vallecano | 24 | 6 | 2 | 16 | 25 | : | 58 | 20 |
| 20. | Betis Sevilla | 24 | 3 | 5 | 16 | 20 | : | 53 | 14 |