| Datum | Spiel | Resultat |
| 28.02.2014 | Athletic Bilbao – Granada | 4:0 |
| 01.03.2014 | Malaga – Valladolid | 16.00 |
| 01.03.2014 | Levante – Osasuna | 18.00 |
| 01.03.2014 | Getafe – Espanyol Barcelona | 20.00 |
| 01.03.2014 | Elche – Celta Vigo | 22.00 |
| 02.03.2014 | Villarreal – Betis Sevilla | 12.00 |
| 02.03.2014 | Atletico Madrid – Real Madrid | 17.00 |
| 02.03.2014 | FC Sevilla – San Sebastian | 19.00 |
| 02.03.2014 | FC Barcelona – Almeria | 21.00 |
| 02.03.2014 | Rayo Vallecano – Valencia | 21.00 |
| R | Mannschaft | Sp | S | U | N | G | : | E | P |
| 1. | Real Madrid | 25 | 20 | 3 | 2 | 71 | : | 24 | 63 |
| 2. | FC Barcelona | 25 | 19 | 3 | 3 | 70 | : | 20 | 60 |
| 3. | Atletico Madrid | 25 | 19 | 3 | 3 | 59 | : | 19 | 60 |
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| 4. | Athletic Bilbao | 26 | 15 | 5 | 6 | 49 | : | 30 | 50 |
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| 5. | Villarreal | 25 | 13 | 4 | 8 | 46 | : | 30 | 43 |
| 6. | San Sebastian | 25 | 12 | 7 | 6 | 46 | : | 35 | 43 |
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| 7. | Valencia | 25 | 10 | 5 | 10 | 38 | : | 36 | 35 |
| 8. | FC Sevilla | 25 | 9 | 8 | 8 | 43 | : | 41 | 35 |
| 9. | Levante | 25 | 8 | 9 | 8 | 24 | : | 31 | 33 |
| 10. | Espanyol Barcelona | 25 | 9 | 5 | 11 | 29 | : | 32 | 32 |
| 11. | Celta Vigo | 25 | 8 | 6 | 11 | 32 | : | 36 | 30 |
| 12. | Osasuna | 25 | 8 | 5 | 12 | 24 | : | 37 | 29 |
| 13. | Granada | 26 | 8 | 3 | 15 | 22 | : | 36 | 27 |
| 14. | Elche | 25 | 6 | 8 | 11 | 22 | : | 37 | 26 |
| 15. | Almeria | 25 | 7 | 5 | 13 | 24 | : | 42 | 26 |
| 16. | Getafe | 25 | 7 | 5 | 13 | 23 | : | 40 | 26 |
| 17. | Malaga | 25 | 6 | 7 | 12 | 23 | : | 34 | 25 |
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| 18. | Valladolid | 25 | 4 | 10 | 11 | 27 | : | 43 | 22 |
| 19. | Rayo Vallecano | 25 | 6 | 2 | 17 | 25 | : | 59 | 20 |
| 20. | Betis Sevilla | 25 | 3 | 5 | 17 | 20 | : | 55 | 14 |