| Datum | Spiel | Resultat |
| 08.03.2014 | Valladolid – FC Barcelona | 1:0 |
| 08.03.2014 | Betis Sevilla – Getafe | 18.00 |
| 08.03.2014 | Celta Vigo – Atletico Madrid | 20.00 |
| 08.03.2014 | Granada – Villarreal | 22.00 |
| 09.03.2014 | Espanyol Barcelona – Elche | 12.00 |
| 09.03.2014 | Almeria – FC Sevilla | 17.00 |
| 09.03.2014 | Real Madrid – Levante | 19.00 |
| 09.03.2014 | Valencia – Athletic Bilbao | 21.00 |
| 10.03.2014 | Osasuna – Malaga | 22.00 |
| 10.03.2014 | San Sebastian – Rayo Vallecano | 22.00 |
| R | Mannschaft | Sp | S | U | N | G | : | E | P |
| 1. | Real Madrid | 26 | 20 | 4 | 2 | 73 | : | 26 | 64 |
| 2. | FC Barcelona | 27 | 20 | 3 | 4 | 74 | : | 22 | 63 |
| 3. | Atletico Madrid | 26 | 19 | 4 | 3 | 61 | : | 21 | 61 |
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| 4. | Athletic Bilbao | 26 | 15 | 5 | 6 | 49 | : | 30 | 50 |
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| 5. | Villarreal | 26 | 13 | 5 | 8 | 47 | : | 31 | 44 |
| 6. | San Sebastian | 26 | 12 | 7 | 7 | 46 | : | 36 | 43 |
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| 7. | FC Sevilla | 26 | 10 | 8 | 8 | 44 | : | 41 | 38 |
| 8. | Levante | 26 | 9 | 9 | 8 | 26 | : | 31 | 36 |
| 9. | Valencia | 26 | 10 | 5 | 11 | 38 | : | 37 | 35 |
| 10. | Espanyol Barcelona | 26 | 9 | 6 | 11 | 29 | : | 32 | 33 |
| 11. | Celta Vigo | 26 | 8 | 6 | 12 | 32 | : | 37 | 30 |
| 12. | Osasuna | 26 | 8 | 5 | 13 | 24 | : | 39 | 29 |
| 13. | Elche | 26 | 7 | 8 | 11 | 23 | : | 37 | 29 |
| 14. | Getafe | 26 | 7 | 6 | 13 | 23 | : | 40 | 27 |
| 15. | Granada | 26 | 8 | 3 | 15 | 22 | : | 36 | 27 |
| 16. | Malaga | 26 | 6 | 8 | 12 | 24 | : | 35 | 26 |
| 17. | Almeria | 26 | 7 | 5 | 14 | 25 | : | 46 | 26 |
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| 18. | Valladolid | 27 | 5 | 11 | 11 | 29 | : | 44 | 26 |
| 19. | Rayo Vallecano | 26 | 7 | 2 | 17 | 26 | : | 59 | 23 |
| 20. | Betis Sevilla | 26 | 3 | 6 | 17 | 21 | : | 56 | 15 |