| Datum | Spiel | Resultat |
| 11.04.2014 | Osasuna – Valladolid | 0:0 |
| 12.04.2014 | Celta Vigo – San Sebastian | 16.00 |
| 12.04.2014 | Villarreal – Levante | 18.00 |
| 12.04.2014 | Granada – FC Barcelona | 20.00 |
| 12.04.2014 | Real Madrid – Almeria | 22.00 |
| 13.04.2014 | Betis Sevilla – FC Sevilla | 12.00 |
| 13.04.2014 | Valencia – Elche | 17.00 |
| 13.04.2014 | Getafe – Atletico Madrid | 19.00 |
| 13.04.2014 | Espanyol Barcelona – Rayo Vallecano | 21.00 |
| 14.04.2014 | Athletic Bilbao – Malaga | 22.00 |
| R | Mannschaft | Sp | S | U | N | G | : | E | P |
| 1. | Atletico Madrid | 32 | 25 | 4 | 3 | 70 | : | 22 | 79 |
| 2. | FC Barcelona | 32 | 25 | 3 | 4 | 92 | : | 26 | 78 |
| 3. | Real Madrid | 32 | 24 | 4 | 4 | 90 | : | 32 | 76 |
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| 4. | Athletic Bilbao | 32 | 17 | 8 | 7 | 55 | : | 35 | 59 |
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| 5. | FC Sevilla | 32 | 15 | 8 | 9 | 59 | : | 47 | 53 |
| 6. | San Sebastian | 32 | 14 | 8 | 10 | 54 | : | 48 | 50 |
| 7. | Villarreal | 32 | 14 | 7 | 11 | 51 | : | 38 | 49 |
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| 8. | Valencia | 32 | 11 | 8 | 13 | 44 | : | 45 | 41 |
| 9. | Levante | 32 | 10 | 10 | 12 | 30 | : | 40 | 40 |
| 10. | Espanyol Barcelona | 32 | 11 | 7 | 14 | 35 | : | 40 | 40 |
| 11. | Malaga | 32 | 10 | 8 | 14 | 35 | : | 40 | 38 |
| 12. | Rayo Vallecano | 32 | 11 | 3 | 18 | 37 | : | 68 | 36 |
| 13. | Celta Vigo | 32 | 10 | 6 | 16 | 34 | : | 47 | 36 |
| 14. | Elche | 32 | 8 | 11 | 13 | 26 | : | 42 | 35 |
| 15. | Granada | 32 | 10 | 4 | 18 | 29 | : | 46 | 34 |
| 16. | Osasuna | 33 | 9 | 7 | 17 | 28 | : | 53 | 34 |
| 17. | Valladolid | 33 | 6 | 14 | 13 | 32 | : | 50 | 32 |
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| 18. | Getafe | 32 | 8 | 7 | 17 | 29 | : | 49 | 31 |
| 19. | Almeria | 32 | 8 | 6 | 18 | 34 | : | 60 | 30 |
| 20. | Betis Sevilla | 32 | 5 | 7 | 20 | 28 | : | 64 | 22 |