| Datum | Spiel | Resultat |
| 01.09.2012 | Celta Vigo – Osasuna | 2:0 |
| 01.09.2012 | Saragossa – Malaga | 0:1 |
| 01.09.2012 | La Coruña – Getafe | 1:1 |
| 01.09.2012 | Mallorca – Real Sociedad | 1:0 |
| 02.09.2012 | Rayo Vallecano – FC Sevilla | 0:0 |
| 02.09.2012 | Athletic Bilbao – Valladolid | 2:0 |
| 02.09.2012 | Levante – Espanyol Barcelona | 3:2 |
| 02.09.2012 | Real Madrid – Granada | 3:0 |
| 02.09.2012 | FC Barcelona – Valencia | 1:0 |
| 26.09.2012 | Betis Sevilla – Atletico Madrid | 2:4 |
| R | Mannschaft | Sp | S | U | N | G | : | E | P |
| 1. | FC Barcelona | 5 | 5 | 0 | 0 | 14 | : | 3 | 15 |
| 2. | Atletico Madrid | 5 | 4 | 1 | 0 | 15 | : | 7 | 13 |
| 3. | Mallorca | 5 | 3 | 2 | 0 | 7 | : | 3 | 11 |
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| 4. | Malaga | 5 | 3 | 2 | 0 | 6 | : | 2 | 11 |
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| 5. | FC Sevilla | 5 | 3 | 2 | 0 | 6 | : | 2 | 11 |
| 6. | Betis Sevilla | 5 | 3 | 0 | 2 | 10 | : | 9 | 9 |
| 7. | Real Madrid | 5 | 2 | 1 | 2 | 7 | : | 4 | 7 |
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| 8. | Levante | 5 | 2 | 1 | 2 | 7 | : | 9 | 7 |
| 9. | Rayo Vallecano | 5 | 2 | 1 | 2 | 6 | : | 7 | 7 |
| 10. | Real Sociedad | 5 | 2 | 0 | 3 | 6 | : | 9 | 6 |
| 11. | Valladolid | 5 | 2 | 0 | 3 | 4 | : | 5 | 6 |
| 12. | La Coruña | 5 | 1 | 3 | 1 | 7 | : | 7 | 6 |
| 13. | Celta Vigo | 5 | 2 | 0 | 3 | 6 | : | 6 | 6 |
| 14. | Saragossa | 5 | 2 | 0 | 3 | 5 | : | 6 | 6 |
| 15. | Valencia | 5 | 1 | 2 | 2 | 6 | : | 8 | 5 |
| 16. | Athletic Bilbao | 5 | 1 | 2 | 2 | 8 | : | 12 | 5 |
| 17. | Getafe | 5 | 1 | 1 | 3 | 6 | : | 10 | 4 |
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| 18. | Granada | 5 | 0 | 2 | 3 | 2 | : | 8 | 2 |
| 19. | Espanyol Barcelona | 5 | 0 | 1 | 4 | 7 | : | 11 | 1 |
| 20. | Osasuna | 5 | 0 | 1 | 4 | 3 | : | 10 | 1 |