| Datum | Spiel | Resultat |
| 26.01.2013 | Celta Vigo – Real Sociedad | 1:1 |
| 26.01.2013 | Levante – Valladolid | 18.00 |
| 26.01.2013 | Saragossa – Espanyol Barcelona | 20.00 |
| 26.01.2013 | La Coruña – Valencia | 22.00 |
| 27.01.2013 | Real Madrid – Getafe | 12.00 |
| 27.01.2013 | Rayo Vallecano – Betis Sevilla | 17.00 |
| 27.01.2013 | FC Barcelona – Osasuna | 19.00 |
| 27.01.2013 | Mallorca – Malaga | 21.00 |
| 27.01.2013 | Athletic Bilbao – Atletico Madrid | 21.00 |
| 28.01.2013 | FC Sevilla – Granada | 21.30 |
| R | Mannschaft | Sp | S | U | N | G | : | E | P |
| 1. | FC Barcelona | 20 | 18 | 1 | 1 | 66 | : | 23 | 55 |
| 2. | Atletico Madrid | 20 | 15 | 2 | 3 | 42 | : | 18 | 47 |
| 3. | Real Madrid | 20 | 12 | 4 | 4 | 50 | : | 20 | 40 |
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| 4. | Betis Sevilla | 20 | 11 | 2 | 7 | 31 | : | 30 | 35 |
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| 5. | Malaga | 20 | 9 | 5 | 6 | 30 | : | 17 | 32 |
| 6. | Rayo Vallecano | 20 | 10 | 1 | 9 | 27 | : | 36 | 31 |
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| 7. | Valencia | 20 | 9 | 3 | 8 | 27 | : | 32 | 30 |
| 8. | Levante | 20 | 9 | 3 | 8 | 24 | : | 29 | 30 |
| 9. | Real Sociedad | 21 | 8 | 6 | 7 | 32 | : | 28 | 30 |
| 10. | Valladolid | 20 | 8 | 4 | 8 | 29 | : | 25 | 28 |
| 11. | Getafe | 20 | 7 | 5 | 8 | 25 | : | 31 | 26 |
| 12. | FC Sevilla | 20 | 6 | 5 | 9 | 24 | : | 29 | 23 |
| 13. | Saragossa | 20 | 7 | 1 | 12 | 21 | : | 30 | 22 |
| 14. | Athletic Bilbao | 20 | 6 | 4 | 10 | 24 | : | 40 | 22 |
| 15. | Espanyol Barcelona | 20 | 5 | 6 | 9 | 23 | : | 32 | 21 |
| 16. | Granada | 20 | 5 | 5 | 10 | 18 | : | 29 | 20 |
| 17. | Celta Vigo | 21 | 5 | 5 | 11 | 21 | : | 26 | 20 |
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| 18. | Osasuna | 20 | 4 | 6 | 10 | 16 | : | 21 | 18 |
| 19. | Mallorca | 20 | 4 | 5 | 11 | 20 | : | 36 | 17 |
| 20. | La Coruña | 20 | 3 | 7 | 10 | 24 | : | 42 | 16 |