| Datum | Spiel | Resultat |
| 23.08.2013 | Getafe – Almeria | 2:2 |
| 23.08.2013 | Athletic Bilbao – Osasuna | 22.00 |
| 24.08.2013 | Elche – Real Sociedad | 19.00 |
| 24.08.2013 | Espanyol Barcelona – Valencia | 21.00 |
| 24.08.2013 | Villarreal – Valladolid | 23.00 |
| 25.08.2013 | Atletico Madrid – Rayo Vallecano | 19.00 |
| 25.08.2013 | Levante – FC Sevilla | 21.00 |
| 25.08.2013 | Malaga – FC Barcelona | 21.00 |
| 25.08.2013 | Betis Sevilla – Celta Vigo | 23.00 |
| 26.08.2013 | Granada – Real Madrid | 21.00 |
| R | Mannschaft | Sp | S | U | N | G | : | E | P |
| 1. | FC Barcelona | 1 | 1 | 0 | 0 | 7 | : | 0 | 3 |
| 2. | Rayo Vallecano | 1 | 1 | 0 | 0 | 3 | : | 0 | 3 |
| 3. | Atletico Madrid | 1 | 1 | 0 | 0 | 3 | : | 1 | 3 |
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| 4. | Real Sociedad | 1 | 1 | 0 | 0 | 2 | : | 0 | 3 |
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| 5. | Villarreal | 1 | 1 | 0 | 0 | 3 | : | 2 | 3 |
| 6. | Athletic Bilbao | 1 | 1 | 0 | 0 | 2 | : | 1 | 3 |
| Granada | 1 | 1 | 0 | 0 | 2 | : | 1 | 3 | |
| Real Madrid | 1 | 1 | 0 | 0 | 2 | : | 1 | 3 | |
| 9. | Valencia | 1 | 1 | 0 | 0 | 1 | : | 0 | 3 |
| 10. | Celta Vigo | 1 | 0 | 1 | 0 | 2 | : | 2 | 1 |
| Espanyol Barcelona | 1 | 0 | 1 | 0 | 2 | : | 2 | 1 | |
| 12. | Almeria | 2 | 0 | 1 | 1 | 4 | : | 5 | 1 |
| 13. | Getafe | 2 | 0 | 1 | 1 | 2 | : | 4 | 1 |
| 14. | Betis Sevilla | 1 | 0 | 0 | 1 | 1 | : | 2 | 0 |
| Osasuna | 1 | 0 | 0 | 1 | 1 | : | 2 | 0 | |
| Valladolid | 1 | 0 | 0 | 1 | 1 | : | 2 | 0 | |
| 17. | Malaga | 1 | 0 | 0 | 1 | 0 | : | 1 | 0 |
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| 18. | FC Sevilla | 1 | 0 | 0 | 1 | 1 | : | 3 | 0 |
| 19. | Elche | 1 | 0 | 0 | 1 | 0 | : | 3 | 0 |
| 20. | Levante | 1 | 0 | 0 | 1 | 0 | : | 7 | 0 |