| Datum | Spiel | Resultat |
| 20.09.2013 | Osasuna – Elche | 2:1 |
| 21.09.2013 | San Sebastian – Malaga | 16.00 |
| 21.09.2013 | Almeria – Levante | 18.00 |
| 21.09.2013 | Rayo Vallecano – FC Barcelona | 20.00 |
| 21.09.2013 | Valladolid – Atletico Madrid | 22.00 |
| 22.09.2013 | Betis Sevilla – Granada | 12.00 |
| 22.09.2013 | Celta Vigo – Villarreal | 17.00 |
| 22.09.2013 | Real Madrid – Getafe | 19.00 |
| 22.09.2013 | Valencia – FC Sevilla | 21.00 |
| 23.09.2013 | Espanyol Barcelona – Athletic Bilbao | 22.00 |
| R | Mannschaft | Sp | S | U | N | G | : | E | P |
| 1. | Atletico Madrid | 4 | 4 | 0 | 0 | 14 | : | 4 | 12 |
| FC Barcelona | 4 | 4 | 0 | 0 | 14 | : | 4 | 12 | |
| 3. | Villarreal | 4 | 3 | 1 | 0 | 10 | : | 5 | 10 |
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| 4. | Real Madrid | 4 | 3 | 1 | 0 | 8 | : | 4 | 10 |
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| 5. | Athletic Bilbao | 4 | 3 | 0 | 1 | 8 | : | 6 | 9 |
| 6. | Espanyol Barcelona | 4 | 2 | 2 | 0 | 6 | : | 3 | 8 |
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| 7. | San Sebastian | 4 | 1 | 2 | 1 | 4 | : | 3 | 5 |
| 8. | Celta Vigo | 4 | 1 | 2 | 1 | 7 | : | 7 | 5 |
| 9. | Levante | 4 | 1 | 2 | 1 | 2 | : | 8 | 5 |
| 10. | Malaga | 4 | 1 | 1 | 2 | 7 | : | 4 | 4 |
| 11. | Betis Sevilla | 4 | 1 | 1 | 2 | 5 | : | 5 | 4 |
| 12. | Granada | 4 | 1 | 1 | 2 | 3 | : | 4 | 4 |
| Valladolid | 4 | 1 | 1 | 2 | 3 | : | 4 | 4 | |
| 14. | Getafe | 4 | 1 | 1 | 2 | 4 | : | 6 | 4 |
| 15. | Valencia | 4 | 1 | 0 | 3 | 5 | : | 9 | 3 |
| 16. | Rayo Vallecano | 4 | 1 | 0 | 3 | 4 | : | 12 | 3 |
| 17. | Elche | 5 | 0 | 3 | 2 | 4 | : | 8 | 3 |
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| 18. | Osasuna | 5 | 1 | 0 | 4 | 4 | : | 10 | 3 |
| 19. | Almeria | 4 | 0 | 2 | 2 | 8 | : | 11 | 2 |
| 20. | FC Sevilla | 4 | 0 | 2 | 2 | 5 | : | 8 | 2 |