| Datum | Spiel | Resultat |
| 20.10.2012 | Malaga – Valladolid | 2:1 |
| 20.10.2012 | Real Madrid – Celta Vigo | 18.00 |
| 20.10.2012 | Valencia – Athletic Bilbao | 20.00 |
| 20.10.2012 | La Coruña – FC Barcelona | 22.00 |
| 21.10.2012 | Getafe – Levante | 12.00 |
| 21.10.2012 | Espanyol Barcelona – Rayo Vallecano | 16.00 |
| 21.10.2012 | Granada – Saragossa | 17.50 |
| 21.10.2012 | Osasuna – Betis Sevilla | 19.45 |
| 21.10.2012 | Real Sociedad – Atletico Madrid | 21.30 |
| 22.10.2012 | FC Sevilla – Mallorca | 21.30 |
| R | Mannschaft | Sp | S | U | N | G | : | E | P |
| 1. | FC Barcelona | 7 | 6 | 1 | 0 | 19 | : | 7 | 19 |
| 2. | Atletico Madrid | 7 | 6 | 1 | 0 | 18 | : | 8 | 19 |
| 3. | Malaga | 8 | 5 | 2 | 1 | 13 | : | 5 | 17 |
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| 4. | Betis Sevilla | 7 | 4 | 0 | 3 | 12 | : | 13 | 12 |
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| 5. | Real Madrid | 7 | 3 | 2 | 2 | 14 | : | 7 | 11 |
| 6. | Mallorca | 7 | 3 | 2 | 2 | 8 | : | 6 | 11 |
| 7. | FC Sevilla | 7 | 3 | 2 | 2 | 8 | : | 7 | 11 |
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| 8. | Getafe | 7 | 3 | 1 | 3 | 8 | : | 10 | 10 |
| 9. | Levante | 7 | 3 | 1 | 3 | 8 | : | 12 | 10 |
| 10. | Rayo Vallecano | 7 | 3 | 1 | 3 | 9 | : | 14 | 10 |
| 11. | Valladolid | 8 | 3 | 1 | 4 | 12 | : | 9 | 10 |
| 12. | Celta Vigo | 7 | 3 | 0 | 4 | 9 | : | 8 | 9 |
| 13. | Real Sociedad | 7 | 3 | 0 | 4 | 8 | : | 11 | 9 |
| 14. | Valencia | 7 | 2 | 2 | 3 | 8 | : | 9 | 8 |
| 15. | Granada | 7 | 2 | 2 | 3 | 6 | : | 10 | 8 |
| 16. | Athletic Bilbao | 7 | 2 | 2 | 3 | 9 | : | 14 | 8 |
| 17. | Saragossa | 7 | 2 | 0 | 5 | 5 | : | 9 | 6 |
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| 18. | La Coruña | 7 | 1 | 3 | 3 | 9 | : | 14 | 6 |
| 19. | Osasuna | 7 | 1 | 1 | 5 | 6 | : | 11 | 4 |
| 20. | Espanyol Barcelona | 7 | 0 | 2 | 5 | 8 | : | 13 | 2 |