| Datum | Spiel | Resultat |
| 27.10.2012 | Espanyol Barcelona – Malaga | 0:0 |
| 27.10.2012 | Betis Sevilla – Valencia | |
| 27.10.2012 | Celta Vigo – La Coruña | |
| 27.10.2012 | Rayo Vallecano – FC Barcelona |
| R | Mannschaft | Sp | S | U | N | G | : | E | P |
| 1. | FC Barcelona | 8 | 7 | 1 | 0 | 24 | : | 11 | 22 |
| 2. | Atletico Madrid | 8 | 7 | 1 | 0 | 19 | : | 8 | 22 |
| 3. | Malaga | 9 | 5 | 3 | 1 | 13 | : | 5 | 18 |
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| 4. | Real Madrid | 8 | 4 | 2 | 2 | 16 | : | 7 | 14 |
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| 5. | FC Sevilla | 8 | 4 | 2 | 2 | 11 | : | 9 | 14 |
| 6. | Betis Sevilla | 8 | 4 | 1 | 3 | 12 | : | 13 | 13 |
| 7. | Levante | 8 | 4 | 1 | 3 | 9 | : | 12 | 13 |
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| 8. | Mallorca | 8 | 3 | 2 | 3 | 10 | : | 9 | 11 |
| 9. | Valencia | 8 | 3 | 2 | 3 | 11 | : | 11 | 11 |
| 10. | Valladolid | 8 | 3 | 1 | 4 | 12 | : | 9 | 10 |
| 11. | Getafe | 8 | 3 | 1 | 4 | 8 | : | 11 | 10 |
| 12. | Rayo Vallecano | 8 | 3 | 1 | 4 | 11 | : | 17 | 10 |
| 13. | Celta Vigo | 8 | 3 | 0 | 5 | 9 | : | 10 | 9 |
| 14. | Saragossa | 8 | 3 | 0 | 5 | 7 | : | 10 | 9 |
| 15. | Real Sociedad | 8 | 3 | 0 | 5 | 8 | : | 12 | 9 |
| 16. | Granada | 8 | 2 | 2 | 4 | 7 | : | 12 | 8 |
| 17. | Athletic Bilbao | 8 | 2 | 2 | 4 | 11 | : | 17 | 8 |
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| 18. | La Coruña | 8 | 1 | 3 | 4 | 13 | : | 19 | 6 |
| 19. | Espanyol Barcelona | 9 | 1 | 3 | 5 | 11 | : | 15 | 6 |
| 20. | Osasuna | 8 | 1 | 2 | 5 | 6 | : | 11 | 5 |