| Datum | Spiel | Resultat |
| 04.01.2014 | Malaga – Atletico Madrid | 0:1 |
| 04.01.2014 | Valladolid – Betis Sevilla | 18.00 |
| 04.01.2014 | Valencia – Levante | 20.00 |
| 04.01.2014 | Almeria – Granada | 22.00 |
| 05.01.2014 | FC Sevilla – Getafe | 12.00 |
| 05.01.2014 | FC Barcelona – Elche | 16.00 |
| 05.01.2014 | Osasuna – Espanyol Barcelona | 18.00 |
| 05.01.2014 | San Sebastian – Athletic Bilbao | 20.00 |
| 06.01.2014 | Real Madrid – Celta Vigo | 19.00 |
| 06.01.2014 | Rayo Vallecano – Villarreal | 22.00 |
| R | Mannschaft | Sp | S | U | N | G | : | E | P |
| 1. | Atletico Madrid | 18 | 16 | 1 | 1 | 47 | : | 11 | 49 |
| 2. | FC Barcelona | 17 | 15 | 1 | 1 | 49 | : | 12 | 46 |
| 3. | Real Madrid | 17 | 13 | 2 | 2 | 49 | : | 21 | 41 |
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| 4. | Athletic Bilbao | 17 | 10 | 3 | 4 | 26 | : | 21 | 33 |
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| 5. | San Sebastian | 17 | 8 | 5 | 4 | 33 | : | 23 | 29 |
| 6. | Villarreal | 17 | 8 | 4 | 5 | 27 | : | 18 | 28 |
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| 7. | FC Sevilla | 17 | 7 | 5 | 5 | 32 | : | 29 | 26 |
| 8. | Getafe | 17 | 7 | 2 | 8 | 20 | : | 27 | 23 |
| 9. | Espanyol Barcelona | 17 | 6 | 4 | 7 | 22 | : | 23 | 22 |
| 10. | Valencia | 17 | 6 | 2 | 9 | 23 | : | 29 | 20 |
| 11. | Granada | 17 | 6 | 2 | 9 | 15 | : | 22 | 20 |
| 12. | Levante | 17 | 5 | 5 | 7 | 17 | : | 25 | 20 |
| 13. | Malaga | 18 | 5 | 5 | 8 | 19 | : | 23 | 20 |
| 14. | Elche | 17 | 4 | 5 | 8 | 16 | : | 23 | 17 |
| 15. | Celta Vigo | 17 | 4 | 4 | 9 | 21 | : | 27 | 16 |
| 16. | Almeria | 17 | 4 | 4 | 9 | 17 | : | 32 | 16 |
| 17. | Osasuna | 17 | 4 | 3 | 10 | 14 | : | 28 | 15 |
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| 18. | Valladolid | 17 | 3 | 6 | 8 | 21 | : | 29 | 15 |
| 19. | Rayo Vallecano | 17 | 4 | 1 | 12 | 16 | : | 40 | 13 |
| 20. | Betis Sevilla | 17 | 2 | 4 | 11 | 15 | : | 36 | 10 |