| Datum | Spiel | Resultat |
| 17.01.2014 | Malaga – Valencia | 0:0 |
| 18.01.2014 | Betis Sevilla – Real Madrid | 16.00 |
| 18.01.2014 | Elche – Rayo Vallecano | 18.00 |
| 18.01.2014 | Granada – Osasuna | 20.00 |
| 18.01.2014 | Espanyol Barcelona – Celta Vigo | 22.00 |
| 19.01.2014 | Getafe – San Sebastian | 12.00 |
| 19.01.2014 | Villarreal – Almeria | 17.00 |
| 19.01.2014 | Levante – FC Barcelona | 19.00 |
| 19.01.2014 | Atletico Madrid – FC Sevilla | 21.00 |
| 20.01.2014 | Athletic Bilbao – Valladolid | 22.00 |
| R | Mannschaft | Sp | S | U | N | G | : | E | P |
| 1. | FC Barcelona | 19 | 16 | 2 | 1 | 53 | : | 12 | 50 |
| 2. | Atletico Madrid | 19 | 16 | 2 | 1 | 47 | : | 11 | 50 |
| 3. | Real Madrid | 19 | 15 | 2 | 2 | 53 | : | 21 | 47 |
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| 4. | Athletic Bilbao | 19 | 11 | 3 | 5 | 32 | : | 24 | 36 |
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| 5. | Villarreal | 19 | 10 | 4 | 5 | 37 | : | 21 | 34 |
| 6. | San Sebastian | 19 | 9 | 5 | 5 | 36 | : | 28 | 32 |
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| 7. | FC Sevilla | 19 | 8 | 6 | 5 | 36 | : | 30 | 30 |
| 8. | Valencia | 20 | 7 | 3 | 10 | 26 | : | 31 | 24 |
| 9. | Getafe | 19 | 7 | 2 | 10 | 20 | : | 31 | 23 |
| 10. | Granada | 19 | 7 | 2 | 10 | 19 | : | 25 | 23 |
| 11. | Levante | 19 | 6 | 5 | 8 | 18 | : | 27 | 23 |
| 12. | Espanyol Barcelona | 19 | 6 | 4 | 9 | 22 | : | 25 | 22 |
| 13. | Osasuna | 19 | 6 | 3 | 10 | 17 | : | 29 | 21 |
| 14. | Malaga | 20 | 5 | 6 | 9 | 19 | : | 24 | 21 |
| 15. | Celta Vigo | 19 | 5 | 4 | 10 | 23 | : | 31 | 19 |
| 16. | Almeria | 19 | 5 | 4 | 10 | 21 | : | 38 | 19 |
| 17. | Elche | 19 | 4 | 6 | 9 | 17 | : | 28 | 18 |
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| 18. | Valladolid | 19 | 3 | 7 | 9 | 21 | : | 33 | 16 |
| 19. | Rayo Vallecano | 19 | 5 | 1 | 13 | 19 | : | 45 | 16 |
| 20. | Betis Sevilla | 19 | 2 | 5 | 12 | 16 | : | 38 | 11 |