| Datum | Spiel | Resultat |
| 07.02.2014 | Espanyol Barcelona – Granada | 1:0 |
| 08.02.2014 | Valencia – Betis Sevilla | 16.00 |
| 08.02.2014 | Rayo Vallecano – Malaga | 18.00 |
| 08.02.2014 | Real Madrid – Villarreal | 20.00 |
| 08.02.2014 | Almeria – Atletico Madrid | 22.00 |
| 09.02.2014 | Osasuna – Getafe | 12.00 |
| 09.02.2014 | Valladolid – Elche | 17.00 |
| 09.02.2014 | San Sebastian – Levante | 19.00 |
| 09.02.2014 | FC Sevilla – FC Barcelona | 21.00 |
| 10.02.2014 | Celta Vigo – Athletic Bilbao | 22.00 |
| R | Mannschaft | Sp | S | U | N | G | : | E | P |
| 1. | Atletico Madrid | 22 | 18 | 3 | 1 | 56 | : | 14 | 57 |
| 2. | FC Barcelona | 22 | 17 | 3 | 2 | 59 | : | 16 | 54 |
| 3. | Real Madrid | 22 | 17 | 3 | 2 | 61 | : | 22 | 54 |
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| 4. | Athletic Bilbao | 22 | 13 | 4 | 5 | 42 | : | 28 | 43 |
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| 5. | Villarreal | 22 | 12 | 4 | 6 | 42 | : | 23 | 40 |
| 6. | San Sebastian | 22 | 10 | 6 | 6 | 42 | : | 34 | 36 |
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| 7. | FC Sevilla | 22 | 8 | 7 | 7 | 41 | : | 37 | 31 |
| 8. | Espanyol Barcelona | 23 | 8 | 5 | 10 | 26 | : | 29 | 29 |
| 9. | Valencia | 22 | 8 | 4 | 10 | 31 | : | 35 | 28 |
| 10. | Levante | 22 | 7 | 7 | 8 | 22 | : | 30 | 28 |
| 11. | Getafe | 22 | 7 | 4 | 11 | 22 | : | 34 | 25 |
| 12. | Celta Vigo | 22 | 7 | 4 | 11 | 29 | : | 35 | 25 |
| 13. | Malaga | 22 | 6 | 6 | 10 | 22 | : | 29 | 24 |
| 14. | Elche | 22 | 6 | 6 | 10 | 20 | : | 32 | 24 |
| 15. | Granada | 23 | 7 | 3 | 13 | 20 | : | 30 | 24 |
| 16. | Almeria | 22 | 6 | 4 | 12 | 22 | : | 41 | 22 |
| 17. | Osasuna | 22 | 6 | 4 | 12 | 19 | : | 37 | 22 |
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| 18. | Valladolid | 22 | 4 | 8 | 10 | 24 | : | 37 | 20 |
| 19. | Rayo Vallecano | 22 | 5 | 2 | 15 | 21 | : | 51 | 17 |
| 20. | Betis Sevilla | 22 | 3 | 5 | 14 | 20 | : | 47 | 14 |