| Datum | Spiel | Resultat |
| 21.03.2014 | Celta Vigo – Malaga | 0:2 |
| 21.03.2014 | Athletic Bilbao – Getafe | 22.00 |
| 22.03.2014 | Granada – Elche | 16.00 |
| 22.03.2014 | Espanyol Barcelona – Levante | 18.00 |
| 22.03.2014 | Valladolid – Rayo Vallecano | 20.00 |
| 23.03.2014 | Osasuna – FC Sevilla | 12.00 |
| 23.03.2014 | Betis Sevilla – Atletico Madrid | 17.00 |
| 23.03.2014 | Valencia – Villarreal | 19.00 |
| 23.03.2014 | Real Madrid – FC Barcelona | 21.00 |
| 24.03.2014 | Almeria – San Sebastian | 22.00 |
| R | Mannschaft | Sp | S | U | N | G | : | E | P |
| 1. | Real Madrid | 28 | 22 | 4 | 2 | 77 | : | 26 | 70 |
| 2. | Atletico Madrid | 28 | 21 | 4 | 3 | 64 | : | 21 | 67 |
| 3. | FC Barcelona | 28 | 21 | 3 | 4 | 81 | : | 22 | 66 |
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| 4. | Athletic Bilbao | 28 | 15 | 7 | 6 | 51 | : | 32 | 52 |
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| 5. | San Sebastian | 28 | 13 | 7 | 8 | 49 | : | 39 | 46 |
| 6. | Villarreal | 28 | 13 | 6 | 9 | 48 | : | 34 | 45 |
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| 7. | FC Sevilla | 28 | 12 | 8 | 8 | 51 | : | 43 | 44 |
| 8. | Valencia | 28 | 10 | 6 | 12 | 39 | : | 39 | 36 |
| 9. | Espanyol Barcelona | 28 | 10 | 6 | 12 | 32 | : | 34 | 36 |
| 10. | Levante | 28 | 9 | 9 | 10 | 26 | : | 35 | 36 |
| 11. | Celta Vigo | 29 | 9 | 6 | 14 | 33 | : | 41 | 33 |
| 12. | Malaga | 29 | 8 | 8 | 13 | 28 | : | 36 | 32 |
| 13. | Granada | 28 | 9 | 4 | 15 | 27 | : | 39 | 31 |
| 14. | Elche | 28 | 7 | 9 | 12 | 24 | : | 40 | 30 |
| 15. | Osasuna | 28 | 8 | 5 | 15 | 24 | : | 48 | 29 |
| 16. | Rayo Vallecano | 28 | 9 | 2 | 17 | 32 | : | 62 | 29 |
| 17. | Getafe | 28 | 7 | 7 | 14 | 26 | : | 45 | 28 |
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| 18. | Almeria | 28 | 7 | 5 | 16 | 27 | : | 52 | 26 |
| 19. | Valladolid | 28 | 5 | 11 | 12 | 30 | : | 48 | 26 |
| 20. | Betis Sevilla | 28 | 4 | 7 | 17 | 23 | : | 56 | 19 |